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Bromination of Unsaturated Dodecahedranes—En Route to C20 Fullerene

✍ Scribed by Emmerich Sackers; Thomas Oßwald; Klaus Weber; Manfred Keller; Dieter Hunkler; Jürgen Wörth; Lothar Knothe; Horst Prinzbach

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
365 KB
Volume
12
Category
Article
ISSN
0947-6539

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Bromination of Unsaturated Dodecahedrane
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## Abstract Allyl 4‐__C__‐[(carboxamido)‐ and (ethoxycarbonyl)methyl]hex‐2‐enopyranosides 18a–c, representing chiral precursors for the carbohydrate‐based construction of the ring systems of thromboxane A~2~ and B~2~ were prepared by means of the Claisen‐type rearrangement of the suitably substitut