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BrNO—thermodynamic properties, the ultraviolet/vis spectrum, and the kinetics of its formation

✍ Scribed by N. Houel; H. Van Den Bergh

Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
371 KB
Volume
9
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

The equilibrium
equation image
has been studied between 275°and 363°K. Third‐law calculations lead to Δ__H__°~298~(1) = ‐11.50 ±0.17 kcal/mol, from which

Absorption bands of BrNO in the ultraviolet with e (γ~max~ = 215 nm) = 1.84±0.17 × 10^4^ 1/mol·cm, and in the red with e (γ~max~ = 708 nm) = 7.7±1.9 1/mol·cm at 298°K have been investigated.

The rate of formation of BrNO has also been measured between 275°and 363°K.

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