Bridging the gap between the gas phase and solution: transition in the kinetics of acid-base reactions
β Scribed by Bohme, Diethard K.; Rakshit, Asit B.; Mackay, Gervase I.
- Book ID
- 127373030
- Publisher
- American Chemical Society
- Year
- 1982
- Tongue
- English
- Weight
- 293 KB
- Volume
- 104
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The rate law -d[O,]/dt = kl[A][OJ + k3[A][03]2/(k4 + kb[02]) has been found to obrain for the reaction of ozone with allene and with 1,2-butadiene. We now find that this rate law also applies to the reaction of ozone with ethylene and presumably with all lower alkenes. This generalizes the inhibiti
The kinetics of the reactions CsH,+OH( t M) +products ( + M ) ( I ) were studied at room temperature by pulse radiolysis of C2H6/H20/SFb mixtures. The ethyl radical decay was followed by monitoring the UV absorption signals at 205 nm. The experimentally determined value of k, is (7.1 f 1.0) x lOto M