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Bridged nicotines. Synthesis of cis-2,3,3a,4,5,9b-hexahydro-1-methyl-1H-pyrrolo[2,3-f]quinoline

โœ Scribed by Chavdarian, Charles G.; Seeman, Jeffrey I.; Wooten, Jan B.


Book ID
127232387
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
401 KB
Volume
48
Category
Article
ISSN
0022-3263

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cis-1-Ethyl-4,4,10-trimethyl-2-tosyl-1,2
โœ Chinnakali, K. ;Sudha, D. ;Jayagopi, M. ;Raghunathan, R. ;Fun, Hoong-Kun ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› International Union of Crystallography ๐ŸŒ English โš– 741 KB

The molecule of the title compound, C~26~H~30~N~2~O~4~S, adopts a folded conformation, with the sulfonyl-bound benzene ring lying over the pyridinone ring [centroid-to-centroid distance = 3.893โ€…(1)โ€…ร…], forming a dihedral angle of 23.87โ€…(5)ยฐ. The pyrrolidine ring adopts a twist conformation and the d