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[BP2]3⊖ and [BAs2]3⊖, Zintl Anions with Propadiene Structure

✍ Scribed by Prof. Dr. Hans-Georg von Schnering; Dr. Mehmet Somer; Dr. Martin Hartweg; Dr. Karl Peters

Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
351 KB
Volume
29
Category
Article
ISSN
0044-8249

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Ba3SiI2, a Double Salt of Barium Iodide
Ba3SiI2, a Double Salt of Barium Iodide and the Zintl Phase Ba2Si
✍ Steffen Wengert; Reinhard Nesper 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 215 KB

Reacting Ba 2 X (X ‫؍‬ Si, Ge) with a melt of BaI 2 , new compounds of the composition Ba 3 I 2 X were found. These are the simplest representatives of double salts between Zintl phases and halides. The isotypic structures were re5ned by single-crystal X-ray data (Fddd, a ‫؍‬ 10.057(2), b ‫؍‬ 14.064