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Boson-realization model for the vibrational spectra of tetrahedral molecules

โœ Scribed by Ma, Zhong-Qi; Hou, Xi-Wen; Xie, Mi


Book ID
125485432
Publisher
The American Physical Society
Year
1996
Tongue
English
Weight
149 KB
Volume
53
Category
Article
ISSN
1050-2947

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The stretching vibration-rotation Hamiltonian of tetrahedral molecules is derived in the local-mode model. The result shows that the effective rotational Hamiltonian of a local-mode state gives rise to symmetric-top rotational energy levels, which are quantitatively in good agreement with experiment