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Boronic Acid Catalyzed Friedel−Crafts Reactions of Allylic Alcohols with Electron-Rich Arenes and Heteroarenes.

✍ Scribed by McCubbin, J. Adam; Hosseini, Hamidreza; Krokhin, Oleg V.


Book ID
121078892
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
943 KB
Volume
75
Category
Article
ISSN
0022-3263

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## Abstract “__Deficient” but “efficient__”, the first example of a catalytic Friedel–Crafts alkylation of arenes, carrying electron‐withdrawing groups, with alcohols is reported. The optimized iron(III) chloride (97%) catalyzed allylation, benzylation and propargylation procedures open an access t