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Boron trifluoride complexes of aromatic aldehydes.1 O- vs. N-complexation of para-dialkylaminobenzaldehydes

โœ Scribed by Mordecai Rabinovitz; Amiram Grinvald

Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
200 KB
Volume
12
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES

Boron trifluoride complexes of aromatic
Boron trifluoride complexes of aromatic aldehydes. The CHO: BF3 pseudosubstituent
โœ M. Rabinovitz; A. Grinvald ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 203 KB

Although boron trifluoride complexes of aromatic aldehydes I have been known since 1878,athere is very little information about their spectral and chemical properties.3s4 They are stable 1 : 1 solid complexes which are readily formed by treating a Ccl, or CHaCl, solution of

Aliphatic C๎—ธH, N-insertion versus aromat
Aliphatic C๎—ธH, N-insertion versus aromatic N-substitution in the reaction of arylnitrenium-boron trifluoride complexes with methylated benzenes
โœ Piero Spagnolo; Paolo Zanirato ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 220 KB

The boron trifluoride promoted decomposition of a number of substituted phenyl azides in toluene, para-xylene, -meta-xylene or mesitylene at 60ยฐC, leads preferentially to fi-benzylamines or diarylamines depending on both ring substituent effect and nucleophilic character of the solvent.