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Boron hydride insertion into the ZrC bond of dimeric (η2-formaldehyde)zirconocene

✍ Scribed by Gerhard Erker; Ursula Hoffmann; Roland Zwettler; Carl Krüger


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
182 KB
Volume
367
Category
Article
ISSN
0022-328X

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Borane Insertion into Group-4 Metal-to-C
✍ Ulrich Blaschke; Gerhard Erker; Roland Fröhlich; Oliver Meyer 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 278 KB 👁 1 views

Metallaoxirane / HBR 2 addition / (Formaldehyde)zirconocene / (Butadiene)zirconocene / Heterocycles / Boron (η 2 -Formaldehyde)zirconocene dimer (8) cleanly adds one or five different elements, namely H, B, C, O, and Zr. The bis(borane) insertion product 17 was characterized by an X-two molar equiva