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Boron atom reactions. Rate constants with the epoxides

✍ Scribed by R. Estes; M.B. Tabacco; T.G. Digiuseppe; P. Davidovits

Publisher: Elsevier Science
Year: 1982
Tongue: English
Weight: 314 KB
Volume: 86
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(82)80177-2

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✦ Synopsis

The reaction rates of atomic boron with various epovrdes have been measured m a Row tube appnratus. The btmolrcular rate constants, in umts of cm3 molecule-' s'-' ,are l,Z-zpo~ypropane (8.6 X IO-t'), 1,2~poxybutanc (8.8 x IO-"), 1,2,3,4drepo\ybutanc

(5.5 X IO-").

I-chloro-2.3epouypropane (5.7 X IO-"),and 1,2spoxy-3.3,3-tnchoroptopsne

(1 5 x 10-i').

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