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Boratabenzene Anions C5B(CN)6− and C5B(CF3)6− and the Superacidic Properties of their Conjugate Acids

✍ Scribed by Agnes Kütt; Ivar Koppel; Ilmar A. Koppel; Ivo Leito

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
174 KB
Volume
10
Category
Article
ISSN
1439-4235

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✍ David J. Brauer; Hans Bürger; Regina Hübinger; Gottfried Pawelke 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 183 KB 👁 1 views

Trimethylamine-bis(trifluoromethyl) boranes R(CF 3 ) 2 B ´NMe 3 (R = cis/trans-CF 3 CF=CF (1/2), HCºC (3), H 2 C=CH (4), C 2 H 5 (5), C 6 H 5 CH 2 (6), C 6 F 5 (7), C 6 H 5 (8)) react with NEt 3 ´3 HF depending on the nature of R at 155±200 °C under replacement of the trimethylamine ligand to form