Borane-Mediated Carbon Dioxide Reduction at Ruthenium: Formation of C1 and C2 Compounds
✍ Scribed by Dr. Sébastien Bontemps; Dr. Laure Vendier; Dr. Sylviane Sabo-Etienne
- Publisher
- John Wiley and Sons
- Year
- 2012
- Tongue
- English
- Weight
- 459 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0044-8249
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adduct of 1 [tBu 4 PcInCl(tmed)], have been studied in toluene with laser pulses at 410 nm. These preliminary results show that 2 exhibits good optical-limiting response at this laser wavelength, whereas no response was found for compound 1 and its tmed adduct. Further studies on the NLO properties
## Abstract Acylation of __N__‐silylated and 2,3‐substituted 1,2‐thiazetidine 1,1‐dioxides (β‐sultams) results in the formation of 4‐acylated β‐sultams 2 and 8. The desilylation of 2 to 3 is easily done with TBAF either on silica gel or in ethanolic solution. The acylated β‐sultams are reduced by s