Samarium Diiodide-Mediated Reductive Coupling of Epoxides and Carbonyl Compounds: A Stereocontrolled Synthesis of C-Glycosides from 1,2-Anhydro Sugars

✍ Scribed by Jose Luis Chiara; Esther Sesmilo

• Publisher: John Wiley and Sons
• Year: 2002
• Tongue: English
• Weight: 105 KB
• Volume: 114
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/1521-3757(20020902)114:17<3376::aid-ange3376>3.0.co;2-l

✦ Synopsis

adduct of 1 [tBu 4 PcInCl(tmed)], have been studied in toluene with laser pulses at 410 nm. These preliminary results show that 2 exhibits good optical-limiting response at this laser wavelength, whereas no response was found for compound 1 and its tmed adduct. Further studies on the NLO properties (including optical-limiting properties) displayed by 2 are currently in progress.