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Boomerang-Type Substitution Reaction: Reactivity of Fullerene Epoxides and a Halofullerenol

✍ Scribed by Zhenshan Jia; Xiang Zhang; Gaihong Zhang; Shaohua Huang; Hao Fang; Xiangqing Hu; Yuliang Li; Liangbing Gan; Shiwei Zhang; Daoben Zhu

Book ID
112005199
Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
337 KB
Volume
2
Category
Article
ISSN
1861-4728

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When treated with electrophilic m-CPBA reagent, dienes 1 were efficiently epoxidized at the silylated 1,2-double bond exclusively. Otherwise, regioselective cyclopropanation of the phosphonylated 3,4-double bond was achieved by using the nucleophilic Corey's reagent.