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ChemInform Abstract: Reactivity of Substituted 3-(Diethylphosphonyl)-1-(trialkylsilyl)alka-1,3-dienes: Regioselective Epoxidation and Cyclopropanation Reactions.

✍ Scribed by Fabien Chevalier; Hashim Al-Badri; Noel Collignon

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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When treated with electrophilic m-CPBA reagent, dienes 1 were efficiently epoxidized at the silylated 1,2-double bond exclusively. Otherwise, regioselective cyclopropanation of the phosphonylated 3,4-double bond was achieved by using the nucleophilic Corey's reagent.

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v