A New Family of Dinuclear Rhodium Comple
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Thomas Pechmann; Carsten D. Brandt; Helmut Werner
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Article
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2004
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John Wiley and Sons
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English
β 238 KB
The reactions of [Rh(2)Cl(kappa(2)-acac)(mu-CPh(2))(2)(mu-SbiPr(3))] (3) and [Rh(2)(kappa(2)-acac)(2)(mu-CPh(2))(2)(mu-SbiPr(3))] (4) with PMe(3) lead to exchange of the bridging ligand and afford the novel PMe(3)-bridged counterparts 5 and 6, in which the phosphane occupies a semibridging (5) or a