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Bonding capabilities of imidazol-2-ylidene ligands in group-10 transition-metal chemistry

โœ Scribed by Udo Radius; F. Matthias Bickelhaupt


Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
740 KB
Volume
253
Category
Article
ISSN
0010-8545

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## Abstract Thermolysis of Ru(IMes)(dppp)(CO)H~2~ (1, IMes=1,3โ€dimesitylโ€1,3โ€dihydroโ€2__H__โ€imidazolโ€2โ€ylidene; dppp=Ph~2~PCH~2~CH~2~CH~2~PPh~2~) in the presence of trimethylvinylsilane yields Ru(IMes')(dppp)(CO)H (2) resulting from intramolecular ArCH~2~โ€“H C๏ฃฟH bond activation of the __N__โ€heterocy