We report femtochemical studies of the organometallic dimetal decacarbonyl. By the use of mass spectrometry, we obtain the temporal dynamics in the channels for metal-metal and metal-ligand bond cleavage. The time scale observed for cleavage and for structural bridging indicates the nature of the re
Bonding capabilities of imidazol-2-ylidene ligands in group-10 transition-metal chemistry
โ Scribed by Udo Radius; F. Matthias Bickelhaupt
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- English
- Weight
- 740 KB
- Volume
- 253
- Category
- Article
- ISSN
- 0010-8545
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Recent advances in the synthesis of stable transition metal complexes with terminal BR, AlR, GaR and InR ligands where R is mostly but not always a p-donor ligand, gave rise to speculation about metal-ligand binding interactions. In response to this, theoretical studies have been carried out, which
## Abstract Thermolysis of Ru(IMes)(dppp)(CO)H~2~ (1, IMes=1,3โdimesitylโ1,3โdihydroโ2__H__โimidazolโ2โylidene; dppp=Ph~2~PCH~2~CH~2~CH~2~PPh~2~) in the presence of trimethylvinylsilane yields Ru(IMes')(dppp)(CO)H (2) resulting from intramolecular ArCH~2~โH C๏ฃฟH bond activation of the __N__โheterocy