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Dipyridylamine Ligands − Synthesis, Coordination Chemistry of the Group 10 Metals and Application of Nickel Complexes in Ethylene Oligomerization

✍ Scribed by Thomas Schareina; Gerhard Hillebrand; Hans Fuhrmann; Rhett Kempe

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
253 KB
Volume
2001
Category
Article
ISSN
1434-1948

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The reaction of one equivalent of dilithiated O(SiMe 2 -Ap-H) 2 Cl(THF) Bu 4 N (5), O(SiMe 2 -Ap) 2 Y(BH 4 ) 2 Na(THF) 2 (6) and O(SiMe 2 -Ap) 2 Y(CH(TMS) 2 ) 2 Li(THF) 3 ( ), respectively. The [Ap-H = -N(2-amino-4-methylpyridine)] (1), generated in situ, with LnCl 3 (Ln = Y, Sm) in THF affords O(Si