Bonding and molecular motions in the 1:1 molecular complexes of 1,4-diazabicyclo[2.2.2]octane with tetrahalomethane as studied by means of NQR
β Scribed by T. Okuda; T. Suzuki; H. Negita
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 342 KB
- Volume
- 111
- Category
- Article
- ISSN
- 0022-2860
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The rotational spectra of 1,2,4-trifluorobenzene, its six 13 C isotopic species, and its argon van der Waals complex were recorded using a molecular beam FT microwave spectrometer. The 13 C r s coordinates of the monomer and the structure of the complex were derived. The argon atom was found to be l
## Abstract The reactions of 2βphenoxyβ3,5βdinitropyridine (**1**) with a series of substituted anilines (**4aβd**) in dimethyl sulfoxide (DMSO) in the presence of 1,4βdiazabicyclo[2.2.2]octane (DABCO) yield the 2βanilino derivatives without the accumulation of intermediates. The kinetics is compat