𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Bond Strengths: The Importance of Hyperconjugation

✍ Scribed by Ingold, K. U.; DiLabio, Gino A.


Book ID
120370572
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
54 KB
Volume
8
Category
Article
ISSN
1523-7060

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Heteroatoms and substituent effects: The
✍ James F. King; Manqing Li; Allan Z. Cheng; Vinod Dave πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 210 KB

We have found that the specific rate of ␣-sulfonyl carbanion formation in a ␀-substituted sulfone shows a sizable dependence on the H C ␣ C ␀ X torsion angle. Defining k N = (k exch ) X /(k exch ) model (where the model has X = H or an alkyl group) we observed for a collection of ␀-alkoxy sulfones (