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Bond Shift Rearrangement of Chloro-, Bromo-, and Iodobullvalene in the Solid State and in Solution. A Carbon-13 and Proton NMR Study

✍ Scribed by Luz, Z.; Olivier, L.; Poupko, R.; Müller, K.; Krieger, C.; Zimmermann, H.


Book ID
126158657
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
176 KB
Volume
120
Category
Article
ISSN
0002-7863

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The 15N results reveal a difference in the extent of intramolecular hydrogen bond formation exhibited by the Schiffs base, compound 2, in solution and the solid state. Comparison of the 15N shielding changes observed, with those arising from protonation, provides the basis for a quantitative estimat