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A solution and solid state 15N NMR study of hydrogen bonding in a Schiffs base

✍ Scribed by J. Sitkowski; L. Stefaniak; I. Wawer; L. Kaczmarek; G.A. Webb

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
153 KB
Volume
7
Category
Article
ISSN
0926-2040

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✦ Synopsis

The 15N results reveal a difference in the extent of intramolecular hydrogen bond formation exhibited by the Schiffs base, compound 2, in solution and the solid state. Comparison of the 15N shielding changes observed, with those arising from protonation, provides the basis for a quantitative estimate of the strength of the hydrogen bonds formed.

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