Blue photo- and electroluminescence based on poly(2-benzoyl-1,4-phenylene) and poly(2,5-dibenzoyl-1,4-phenylene)
β Scribed by H. Fu; H. Yun; T. K. Kwei; Y. Okamoto; S. Blumstengel; A. Walser; R. Dorsinville
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 166 KB
- Volume
- 10
- Category
- Article
- ISSN
- 1042-7147
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β¦ Synopsis
Poly(2-benzoyl-1,4-phenylene) (PBP) and poly(2,5-dibenzoyl-1,4-phenylene) (PDBP) were synthesized by coupling polymerization using a Ni catalyst of 2,5dichlorobenzophenone and 2,5-dichloro-1,4-dibenzophenone, respectively. These polymers are soluble in common organic solvents, have high thermal stability and show bright blue photoluminescence. Light-emitting diodes fabricated with these polymers as the active layer emit blue electroluminescence with wavelength at 433 nm for PBP and 475 nm for PDBP.
π SIMILAR VOLUMES
The thermal oxidation and photo-oxidation of poly(2,6-dimethyl-l,4phenylene oxide) have been examined. Oxidation of the plastic results in the evolution of carbon dioxide, nitrogen and traces of hydrogen, the introduction of considerable crosslinking, and increased absorption in the hydroxyl and car