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Bitopic Bis- and Tris(1-pyrazolyl)borate Ligands: Syntheses and Structural Characterization

โœ Scribed by Bieller, Susanne; Zhang, Fan; Bolte, Michael; Bats, Jan W.; Lerner, Hans-Wolfram; Wagner, Matthias


Book ID
115496897
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
146 KB
Volume
23
Category
Article
ISSN
0276-7333

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Tris(pyrazolyl)methane Ligands: Synthese
โœ Alberto Sรกnchez-Mรฉndez; Gustavoย F. Silvestri; Ernesto deย Jesรบs; F.ย Javier deย laย  ๐Ÿ“‚ Article ๐Ÿ“… 2004 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 197 KB

## Abstract The substituted ligands Me~3~SiC(pz)~3~ (1) and Me~3~SiOCH~2~C(pz)~3~ (2) have been prepared starting from HC(pz)~3~ and HOCH~2~C(pz)~3~. The molecular structure of compound 1 has been determined by Xโ€ray diffraction studies, which show a propellerโ€like conformation of the pyrazolyl rin