The title compound, [Co~2~(HO~3~PCH~2~CH~2~COO)~2~(C~10~H~8~N~2~)~2~(H~2~O)~2~], was obtained by a hydrothermal method. Two six-coordinate cobalt(II) ions are linked by two 2-carboxyethylphosphonate ligands, forming a centrosymmetric dimer. The dimers are further interlinked by O—H...O hydrogen bond
Bis(μ-2-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)zinc(II)]
✍ Scribed by Ying, Shao-Ming ;Li, Xin-Fa ;Chen, Wen-Tong ;Liu, Dong-Sheng ;Liu, Jiu-Hui
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 286 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
Bis(l-2-carboxylatoethylphosphonato)bis[aqua(2,2 0 0 0 -bipyridine)zinc(II)]
📜 SIMILAR VOLUMES
l-Benzene-1,2,4,5-tetracarboxylato-bis-[aquabis(2,2 0 0 0 -bipyridine)cobalt(II)] dodecahydrate
The title complex, [Zn(C 5 H 3 O 3 ) 2 (C 10 H 8 N 2 )(H 2 O)], has a slightly distorted square-pyramidal geometry around the Zn II ion and forms a three-dimensional supramolecular structure via O-HÁ Á ÁO, C-HÁ Á ÁO andinteractions.
Single-crystal X-ray study T = 298 K Mean (C-C) = 0.006 A R factor = 0.034 wR factor = 0.085 Data-to-parameter ratio = 12.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.