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Bis(η5-methyl­cyclo­penta­dien­yl)(5-nitro­salicylato-κ2O1,O2)titanium(IV)

✍ Scribed by Gao, Zi-Wei ;Xu, Fang ;Zhang, Cai-Yun ;Gao, Ling-Xiang

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
96 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

Single-crystal X-ray study T = 298 K Mean (C-C) = 0.004 A Disorder in main residue R factor = 0.034 wR factor = 0.091 Data-to-parameter ratio = 12.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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Single-crystal X-ray study T = 298 K Mean (C-C) = 0.005 A Disorder in main residue R factor = 0.045 wR factor = 0.126 Data-to-parameter ratio = 12.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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In the molecule of the title compound, [FeRu(C 3 H 5 )(C 5 H 5 )-(C 10 H 15 )(CO) 4 ]PF 6 , two metal centers are bridged by an allyl chain, resulting in a chiral heterobimetallic molecular ion, with hexafluorophosphate as counter-ion. Both enantiomers are present in the crystal structure, forming a