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Bis(triphenylphosphine)pyridine- and pyrazine-carboxylatecopper(I) complexes

✍ Scribed by F. Cariati; L. Naldini; A. Panzanelli; F. Demartini; M. Manassero

Book ID
108324844
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
539 KB
Volume
69
Category
Article
ISSN
0020-1693

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Di-μ-pyridine-2-thiol­ato-bis­[chloro­(t
Di-μ-pyridine-2-thiol­ato-bis­[chloro­(triphenyl­phosphine)copper(I)]
✍ Marjani, Katayoun ;Davies, Sian C. ;Durrant, Marcus C. ;Hughes, David L. ;Khodam 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 367 KB

The structure of the title compound, [Cu~2~(C~5~H~5~NS)~2~Cl~2~(C~18~H~15~P)~2~], shows two independent molecules, each a dimer bridged through a Cu~2~S~2~ rectangular plane involving the two pyridinethione S atoms and lying about a centre of symmetry. The Cu atoms have a distorted tetrahedral geome