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Bis(triphenylphosphine)iminium pentadecacarbonyliodopentaosmate

✍ Scribed by Rivera, A. V. ;Sheldrick, G. M. ;Hursthouse, M. B.


Book ID
114525577
Publisher
International Union of Crystallography
Year
1978
Weight
425 KB
Volume
34
Category
Article
ISSN
0567-7408

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Bis­(tri­phenyl­phosphine)­iminium tri­c
✍ Evans, Cameron ;Nicholson, Brian K. ;Oliver, Allen G. 📂 Article 📅 2001 🏛 International Union of Crystallography 🌐 English ⚖ 174 KB

The crystal structure of bis(triphenylphosphine)iminium cyclopentadienyltricarbonylmolybdate, [PPN][Mo(CO) 3 ( 5 -C 5 H 5 )] (PPN + = [(PPh 3 ) 2 N] + , C 36 H 30 NP 2 ), is reported. The anion is con®gured in the `piano-stool' arrangement while the cation adopts a bent con®guration about the PÐNÐP