Bis(trimethylsilyl)diazene as a Complex Ligand
✍ Scribed by Prof. Dr. Nils Wiberg; Dipl.-Chem. H. W. Häring; Oswald Schieda
- Publisher
- John Wiley and Sons
- Year
- 1976
- Tongue
- English
- Weight
- 237 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
This product could be obtained pure (isolated yield ca. 5 %) by preparative gas chromatography under mild conditions. Its CCl,) showed it to have the structure of a hexacyclo-[4.4.0.02~4.03~9.05~7.08~'o]decane ( 4 ) . The spectrum contained three signals in the intensity ratio 3:1:6 [T = 7.16 (m, 3
H 3 (SiMe 3 ) 2 ligands / Cobalt / Coordination chemistry / Crystallography The thermal or photochemical reaction of [CpЈЈCo(CO) 2 ] (1) as well as [{CpЈЈCo} 2 (µ-η 2 :η 2 -P 2 ) 2 ] (4). Cobalt complexes 2, 3, and 4 have been characterized by an X-ray crystal-struc-[CpЈЈ = C 5 H 3 (SiMe 3 ) 2 -1,3]