✦ LIBER ✦

Cobalt Complexes with 1,3-Bis(trimethylsilyl)cyclopentadienyl and Substituent-Free Pn Ligands

✍ Scribed by Otto J. Scherer; Thomas Völmecke; Gotthelf Wolmershäuser

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 258 KB
Volume: 1999
Category: Article
ISSN: 1434-1948
DOI: 10.1002/(sici)1099-0682(199906)1999:6<945::aid-ejic945>3.0.co;2-i

No coin nor oath required. For personal study only.

✦ Synopsis

H 3 (SiMe 3 ) 2 ligands / Cobalt / Coordination chemistry / Crystallography The thermal or photochemical reaction of [CpЈЈCo(CO) 2 ] (1) as well as [{CpЈЈCo} 2 (µ-η 2 :η 2 -P 2 ) 2 ] (4). Cobalt complexes 2, 3, and 4 have been characterized by an X-ray crystal-struc-[CpЈЈ = C 5 H 3 (SiMe 3 ) 2 -1,3] with white phosphorus (P 4 ) gives [{CpЈЈCo} 2 (P 5 -P 5 ){CoCpЈЈ} 2 ] (2) and [{CpЈЈCo} 3 P 4 (µ-CO)] (3) ture determination.

📜 SIMILAR VOLUMES

Complexes with Sterically Demanding Liga

Complexes with Sterically Demanding Ligands, XI Synthesis and Properties of Trimethyl[ 1,2,4-tris(trimethylsilyl)cyclopentadienyl] titanium

✍ Okuda, Jun 📂 Article 📅 1990 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 197 KB 👁 1 views

Bis[citrato(3−)-O1,O3,O6]silicate: A Dia

Bis[citrato(3−)-O1,O3,O6]silicate: A Dianionic Complex with Hexacoordinate Silicon(IV) and Two Tridentate Dioato(2−)olato(1−) Ligands

✍ Reinhold Tacke; Martin Penka; Friedrich Popp; Ingo Richter 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 290 KB 👁 1 views

Enantioselective Hydrogenation over Chir

Enantioselective Hydrogenation over Chiral Cobalt Complexes with (+)-(1S,2S,5R)-Neomenthyldiphenylphosphine and (-)-(R,R)-2,2-Dimethyl-4,5-bis(diphenylphosphinomethyl)-1,3-dioxolane.

✍ L. O. Nindakova; B. A. Shainyan; F. K. Shmidt 📂 Article 📅 2005 🏛 John Wiley and Sons ⚖ 15 KB

Preparation and Crystal Structures of Ma

Preparation and Crystal Structures of Manganese, Iron, and Cobalt Complexes of the Bis[di(2-pyridyl)methyl]amine (bdpma) Ligand and Its Oxidative Degradation Product 1,3,3-Tris(2-pyridyl)-3H-imidazo[1,5-a]pyridin-4-ium (tpip); Origin of the bdpma Fragility

✍ Catherine Hemmert; Michael Renz; Heinz Gornitzka; Stéphanie Soulet; Bernard Meun 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 236 KB 👁 2 views

The synthesis and structural characterization of manganese, iron, and cobalt complexes of bis[di(2-pyridyl)methyl]amine (bdpma) were investigated. The bdpma ligand can give rise to mono-or dimeric complexes. Moreover, bdpma can undergo oxidative degradation leading to 1,3,3-tris(2-pyridyl)-3Himidazo

Structural Studies of a Copper(II) Compl

Structural Studies of a Copper(II) Complex with Inequivalent 2-Acetylpyridine 3-Piperidylthiosemicarbazonato Ligands and a Nickel(II) Complex with Different Modes of Coordination by the Two Thiosemicarbazonato Moieties of 1-Phenylglyoxal Bis{N(4)-diethylthiosemicarbazone}

✍ Elena Bermejo; Alfonso Castiñeiras; Lily J. Ackerman; Matthew D. Owens; Douglas 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 128 KB 👁 2 views

The crystal structure of a copper(II) complex of 2acetylpyridine 3-piperidylthiosemicarbazone, [Cu(Acpip) 2 ], indicates a tridentate, monoanionic ligand (i. e., pyridine nitrogen, imine nitrogen and thiolato sulfur atoms) and a bidentate, monanionic ligand (i. e., imine nitrogen and thiolato sulfur

New Rare Earth Metal Complexes with Nitr

New Rare Earth Metal Complexes with Nitrogen-Rich Ligands: 5,5′-Bitetrazolate and 1,3-Bis(tetrazol-5-yl)triazenate—On the Borderline between Coordination and the Formation of Salt-Like Compounds

✍ Patrick J. Eulgem; Axel Klein; Nicola Maggiarosa; Dieter Naumann; Roland W. H. P 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 412 KB 👁 2 views

## Abstract From the two nitrogen‐rich ligands BT^2−^ (BT=5,5′‐bitetrazole) and BTT^3−^ (BTT=1,3‐bis(1__H__‐tetrazol‐5‐yl)triazene), a series of novel rare earth metal complexes were synthesised. For the BT ligand, a vast number of these complexes could be structurally characterised by single‐cryst