Bis(trifluoromethyl)sulfene (CF3)2CSO2, Isolated as Adduct
β Scribed by Dr. Uwe Hartwig; Dr. Hans Pritzkow; Dipl.-Chem. Klaus Rall; Prof. Dr. Wolfgang Sundermeyer
- Publisher
- John Wiley and Sons
- Year
- 1989
- Tongue
- English
- Weight
- 321 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0044-8249
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Further investigations have shown that ( I ) is also formed on reaction of Hg(CN), or Hg(SCH,), with HP(CF,),, the reaction rate decreasing in the order Hg(CN), > Hg(CH=CH,), > Hg(SCH,), > Hg(CH,),.
The complexes [RhCl (3Γn) (MeCN) n (CF 3 triphos)](CF 3 SO 3 ) n (n 1, 2; CF 3 triphos MeC[CH 2 P(m-CF 3 C 6 H 4 ) 2 ] 3 ) and [M(MeCN) 3 (CF 3 triphos)](CF 3 SO 3 ) n (M Ru, n 2; M Ir, n 3) are catalyst precursors for some typical acetalization and transacetalization reactions. The activity of thes