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Bis(trifluoromethyl)phosphoryl-.mu.-oxo-bis(trifluoromethyl)phosphine. The mixed anhydride of a phosphinous and phosphinic acid

✍ Scribed by Burg, Anton B.

Book ID
125995859
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
448 KB
Volume
17
Category
Article
ISSN
0020-1669

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## The kinetics of l&and substitution on the jive-coordinate 1,2-dithiolene complexes [M(&C,(CF,)& X]' (M = Fe, Co; X = a phosphine or phosphite ) are reported. The mechanism is associative for z = 0 and dissociative for z = -1.