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Bis(tricarbonyliron)-para-quinodimethanes: Preparation and Molecular Structure

✍ Scribed by Dr. Ali R. Koray; Claus Krieger; Prof. Dr. Heinz A. Staab

Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
249 KB
Volume
24
Category
Article
ISSN
0044-8249

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A series of 1,8-bis(phosphino)naphthalenes 2 was prepared by treating 1,8-dilithionaphthalene with the appropriate chloro-or bromophosphines RRЈPX; R, RЈ ‫ס‬ Me (for 2a), iPr (for 2c), Cy (for 2d), Ph (for 2f); R ‫ס‬ tBu, RЈ ‫ס‬ Ph (for 2e) (X ‫ס‬ Cl) and R, RЈ ‫ס‬ Et; X ‫ס‬ Br (for 2b). The resulti