Bis(tri-tert-butylphosphine)platinum(0)
✍ Scribed by Moynihan, K. J. ;Chieh, C. ;Goel, R. G.
- Book ID
- 114526581
- Publisher
- International Union of Crystallography
- Year
- 1979
- Weight
- 297 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0567-7408
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The title compound, [Pt(C 12 H 27 P) 2 (C 14 H 8 N) 2 ], is a mononuclear Pt II di-yne exhibiting %-conjugation along the molecular backbone. It is used as a model species for rigidrod platinum poly yne compounds of which it is a precursor. Such compounds are of interest due to the extended %conjuga
## Abstract Tri‐__tert__‐butylphosphin reagiert mit Germaniumtetrachlorid und Zinntetrachlorid im Molverhältnis 1:1 zu neuen Verbindungen der Zusammensetzung (t‐C~4~H~9~)~3~PMCl~4~ (MGe, Sn). Der Vergleich von Kernresonanz‐ und Schwingungsspektren sowie von Leitfähigkeiten mit den entsprechenden D
Single-crystal X-ray study T = 173 K Mean '(C±C) = 0.005 A Ê R factor = 0.043 wR factor = 0.126 Data-to-parameter ratio = 19.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.