Single-crystal X-ray study T = 100 K Mean (C-C) = 0.007 A Disorder in solvent or counterion R factor = 0.041 wR factor = 0.095 Data-to-parameter ratio = 29.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Bis(tetra-n-butylammonium) tetrabromidozincate(II)
✍ Scribed by Gao, Feng-Xian ;Gu, Wen ;Yang, Yong-Sheng ;Qian, Jing ;Yan, Shi-Ping
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 239 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title complex, [(C 4 H 9 ) 4 N] 2 [ZnBr 4 ], the Zn II ion is coordinated by four Br atoms, forming a slightly distorted tetrahedral geometry. The Zn-Br bonds range from 2.3986 (11) to 2.4162 (11) A ˚and the Br-Zn-Br angles range from 106.59 (4) to 112.84 (4) . One of the cations is disordered essentially equally over two orientations.
Related literature
Some research related to zinc(II) compounds has already been published (Wang,
📜 SIMILAR VOLUMES
The structure of the title compound, C 16 H 36 N + ÁPF 6 À , has been reported previously by Angaridis, Cotton & Petrukhina [Inorg. Chim. Acta (2001), 324, 318±323]. However, these authors found the PF 6 À ion to be heavily disordered and they did not publish any coordinates. We present here a redet