Bis(pyridylimino)isoindolato−Iridium Complexes as Epoxidation Catalysts for Alkenes
✍ Scribed by Camerano, José A.; Sämann, Christoph; Wadepohl, Hubert; Gade, Lutz H.
- Book ID
- 126088020
- Publisher
- American Chemical Society
- Year
- 2011
- Tongue
- English
- Weight
- 927 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0276-7333
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The exchange reactions between Ti compounds and hexagonal mesoporous silicas (HMS) have been investigated in detail by means of UV-Vis diffuse reflection spectra, FT-IR, N 2 volumetric adsorption, chemical and elemental analyses. It was found that the exchange of titanium tetraisoproxide (Ti(O i Pr)
## Abstract Several zwitterionic iridium complexes based on chiral P,N‐ligands with imidazoline or oxazoline donors and anionic tetraarylborate or aryltrifluoroborate substituents have been synthesized. The corresponding cationic analogues have also been prepared, to evaluate the effect of the cova