Primary, secondary and tertiary enaminones react with his(pyridine)iodonium(I) tetrafluoroborate in methylene chloride at room temperature to give c~-iodo enaminones in almost quantitative yields. The reported reaction is the first known example of direct iodination of tertiary enaminones.
✦ LIBER ✦
Bis(pyridine)iodonium(I) tetrafluoroborate
✍ Scribed by Álvarez-Rúa, Carmen ;García-Granda, Santiago ;Ballesteros, Alfredo ;González-Bobes, Francisco ;González, José M.
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 330 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 120 K Mean '(C±C) = 0.007 A Ê R factor = 0.036 wR factor = 0.141 Data-to-parameter ratio = 14.7
For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
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