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Bis(phenylenedithlo)tetrathiafulvalene (BPhDT-TTF): Synthesis and properties of a new π-donor for organic metals

✍ Scribed by H. Müller; S. Fiedler; M. Saad; C. Riekel


Book ID
117541532
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
241 KB
Volume
86
Category
Article
ISSN
0379-6779

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Tetrathiafulvalene (TTF) fused to acenap
✍ Martin R. Bryce; Alexander K. Lay; Andrei S. Batsanov; Judith A.K. Howard 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 210 KB

The reaction of transient 1,3-dithiole-2,4,5-trithioue 4 with acenaphthylene afforded the Diels-Alder adduct 5, which was dehydrogenated to yield 6; cross-coupling of 6 with 7 gave the tetrathiafulvalene (TIT) derivative 8, which was converted into the di(methylsulfanyl) analogue 10, the solution el