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Bismuth(III) Trifluoromethanesulfonate: A Chameleon Catalyst for the Friedel–Crafts Acylation

✍ Scribed by Sigrid Répichet; Christophe Le Roux; Jacques Dubac; Jean-Roger Desmurs


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
108 KB
Volume
1998
Category
Article
ISSN
1434-193X

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ChemInform Abstract: Surprising Catalyti
✍ J. R. DESMURS; M. LABROUILLERE; C. LE ROUX; H. GASPARD; A. LAPORTERIE; J. DUBAC 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

Surprising Catalytic Activity of Bismuth(III) Triflate in the Friedel-Crafts Acylation Reaction. -Bismuth(III) triflate is found to be a highly active catalyst for Friedel-Crafts acylations. The reaction of activated and deactivated arenes proceeds in high yields and gives mainly the p-substituted