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Bismuth Triflate-Chiral Bipyridine Complex Catalyzed Asymmetric Ring Opening Reactions of meso-Epoxide in Water.

✍ Scribed by Chikako Ogawa; Stephane Azoulay; Shu Kobayashi


Publisher
John Wiley and Sons
Year
2006
Weight
19 KB
Volume
37
Category
Article
ISSN
0931-7597

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Asymmetric Ring Opening of meso-Epoxides
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## Abstract The catalytic asymmetric ring opening of __meso__‐epoxides with aromatic amines was achieved using a new proline‐based __N__,__Nβ€²__‐dioxide‐indium tris(triflate) complex in high yields (up to 99%) with excellent enantioselectivities (up to 99% __ee__) under mild conditions. The coordina