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Bismuth Triflate Catalyzed Mukaiyama Aldol Reaction in an Ionic Liquid.

✍ Scribed by Thierry Ollevier; Valerie Desyroy; Blandine Debailleul; Sophie Vaur


Publisher
John Wiley and Sons
Year
2006
Weight
31 KB
Volume
37
Category
Article
ISSN
0931-7597

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Bismuth triflate catalyzed prins-type cy
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## Abstract The reaction of aldehydes with homoallylic alcohols in the presence of catalytic amount of bismuth triflate in [bmim]PF~6~generates 4‐tetrahydropyranol derivatives in excellent yield and with high diastereoselectivity. Β© 2008 Wiley Periodicals, Inc. Heteroatom Chem 19:104–106, 2008; Pub