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Bismuth triflate catalyzed prins-type cyclization in ionic liquid: Synthesis of 4-tetrahydropyranol derivatives

✍ Scribed by M. S. R. Murty; K. Rajasekhar; V. Harikrishna; J. S. Yadav

Publisher: John Wiley and Sons
Year: 2008
Tongue: English
Weight: 309 KB
Volume: 19
Category: Article
ISSN: 1042-7163
DOI: 10.1002/hc.20403

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✦ Synopsis

Abstract

The reaction of aldehydes with homoallylic alcohols in the presence of catalytic amount of bismuth triflate in [bmim]PF~6~generates 4‐tetrahydropyranol derivatives in excellent yield and with high diastereoselectivity. © 2008 Wiley Periodicals, Inc. Heteroatom Chem 19:104–106, 2008; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20403

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