In the centrosymmetric dinuclear title complex, [RuCl 2 ( 6 -C 6 H 6 )] 2 Á2CHCl 3 or [Ru 2 Cl 4 (C 6 H 6 ) 2 ]Á2CHCl 3 , accessible from RuCl 3 .nH 2 O and 1,3-cyclohexadiene, the benzene ligands are involved in slipped-parallelstacking interactions with neighbouring molecules, thus forming one-dim
Bis[dichloro-η6-indaneruthenium(II)] dichloroform solvate
✍ Scribed by Vieille-Petit, Ludovic ;Therrien, Bruno ;Süss-Fink, Georg
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 190 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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The crystal structure of [RuCl 2 (C 13 H 13 N 3 ) 2 ] contains complexes on general positions and complexes located on crystallographic twofold rotation axes. The three independent 2-phenylazo-4,6-dimethylpyridine ligands all have the same conformation.
Bis{tri-l-chloro-bis[(g 6 -p-cymene)ruthenium(II)]} di-l-chloro-bis[dichloromercurate(II)]
The title compound, [PtCl 2 {P(C 6 H 5 ) 2 Fe(C 5 H 4 ) 2 P(C 6 H 5 ) 2 }]Á-CHCl 3 , crystallizes with an accompanying chloroform solvent molecule. The Pt atom shows square-planar coordination.
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.007 A Ê R factor = 0.050 wR factor = 0.126 Data-to-parameter ratio = 11.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.