Bis(bis(trimethylsilyl)phosphino)silan [(Me3Si)2P]2SiH2 und 1,2-Bis(bis(trimethylsilyl)phosphino)disilan [(Me3Si)2PSiH2]2
β Scribed by K. Hassler; U. Katzenbeisser
- Book ID
- 103226181
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 170 KB
- Volume
- 399
- Category
- Article
- ISSN
- 0022-328X
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
1-Trimethylsiloxyalkyl-bis(trimethylsilyl)silanes ( 5), obtained by a base induced isomerization of easily accessable 1-hydroxyalkyl-tris(trimethylsilyl)silanes (1) were hydrolized to give 1-hydroxyalkyl-bis(trimethylsilyl)silanes ( 6), which in presence of sodium hydride underwent a further 1,3-Si,
The dinuclear molecule of p-{[(Me 3 Si) 2 CH]Sn(Cl) 2 CH 2 SiMe 2 } 2 C 6 H 4 is centrosymmetric and adopts an `S' conformation that is stabilized by intramolecular CΓHΓΓΓp interactions. The tin atom exists within a distorted tetrahedron defined by a C 2 Cl 2 donor set.