Bis(2,2′-dipyridylamine)dimethanolcopper(II) hexafluorosilicate
✍ Scribed by Casellas, Helene ;Pevec, Andrej ;Kozlevcar, Bojan ;Gamez, Patrick ;Reedijk, Jan
- Book ID
- 104484220
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 255 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
ORTEPII plot (Johnson, 1976) of the structure of the title compound (40% displacement ellipsoids). Unlabelled atoms of the cation are related to labelled atoms by (Àx, Ày, Àz).
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.009 A Ê Disorder in main residue R factor = 0.068 wR factor = 0.203 Data-to-parameter ratio = 15.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.013 A Ê R factor = 0.041 wR factor = 0.110 Data-to-parameter ratio = 14.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, disodium bis(2-aminopyridinium) hexa-μ~3~-hydroxidohexa-μ~2~-oxidododecaoxidohexamolybdonickel;ate(II) dihydrate, Na~2~(C~5~H~7~N~2~)~2~[H~6~NiMo~6~O~24~]·2H~2~O, features β-type Anderson heteropolyoxometalate anions (Ni site symmetry \overline{1}). These anions are connected to