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Bis(2,2′-bipyridine)ruthenium(II) complexes with imidazo[4,5-f ][1,10]-phenanthroline or 2-phenylimidazo[4,5-f ][1,10]phenanthroline

✍ Scribed by Wu, Jian-Zhong; Ye, Bao-Hui; Wang, Lei; Ji, Liang-Nian; Zhou, Jian-Ying; Li, Run-Hua; Zhou, Zhong-Yuan

Book ID
120602264
Publisher
The Royal Society of Chemistry
Year
1997
Tongue
English
Weight
453 KB
Volume
8
Category
Article
ISSN
1472-7773

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In the title complex, [Cd(C 2 H 3 O 2 ) 2 (C 17 H 10 N 4 O) 2 ], the central Cd II ion (site symmetry 2) shows an uncommon eightcoordinate CdN 4 O 4 coordination geometry arising from two N,N-chelating 2-(2-furyl)-1H-imidazo[4,5-f]-1,10-phenanthroline molecules and two O,O-bidentate acetate anions.

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In the title compound, C~33~H~25~N~5~, the central benzene ring is not coplanar with any other rings. The molecules are linked through an intermolecular C—H...N hydrogen bond.