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Bis(2-pyridyl­ethyl)­ammonium perchlorate

✍ Scribed by Butcher, Ray J. ;Gultneh, Yilma ;Khan, A. Raza


Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
259 KB
Volume
58
Category
Article
ISSN
1600-5368

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Bis(2-pyridyl­methyl)­ammonium perchlora
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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.006 A Ê Disorder in solvent or counterion R factor = 0.055 wR factor = 0.156 Data-to-parameter ratio = 9.8 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê Disorder in solvent or counterion R factor = 0.043 wR factor = 0.113 Data-to-parameter ratio = 10.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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In the title compound, [Cu(C 16 H 16 N 4 ) 2 ](ClO 4 ) 2 , the Cu II atom lies on an inversion centre and has a distorted square-planar geometry. In each ligand, the dihedral angle between the triazole and pyridine rings is 9.1 (3) , and that between the triazole and benzene rings is 85.01 ( 14) .