Bis(2-azidoethyl) isophthalate
✍ Scribed by Zhang, Xiao-Ru ;Zhang, Shu-Sheng ;Xu, Min-Hua ;Li, Xue-Mei
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 208 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, C 11 H 11 N 7 O 4 , possesses crystallographically imposed C 2 symmetry. The two side chains are twisted in opposite directions from the mean plane of the pyridine ring. C-HÁ Á ÁO interactions link symmetry-related molecules into two-dimensional layers perpendicular to the a axis
In the centrosymmetric title compound, [Zn(C 15 H 13 N 2 O 2 ) 2 -(C 5 H 5 N) 2 ], the Zn atom is chelated by the O and N atoms of two bidentate ligands. The coordination geometry of the central Zn atom is octahedral. The crystal packing is stabilized by intermolecular CÐHÁ Á ÁO interactions.
The title compound, [Mn~2~(N~3~)~4~(C~14~H~17~N~3~)~2~], comprises two [Mn(bpea)(N~3~)]^+^ fragments [where bpea is the tridentate ligand __N__,__N__-bis(2-pyridylmethyl)ethylamine] bridged by two azide anions to form a centrosymmetric dinuclear complex. The coordination environment around the Mn^II
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.025 wR factor = 0.071 Data-to-parameter ratio = 14.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.