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Bis{2-[(3,5-dibromo-2-oxidophenyl)methylamino]ethanol-κ3O,N,O′}nickel(II)

✍ Scribed by Zhang, Shu-Hua ;Zou, Hua-Hong ;Zeng, Ming-Hua ;Liang, Hong

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
938 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title centrosymmetric complex, [Ni(C 9 H 10 Br 2 NO 2 ) 2 ], the Ni II ion is chelated by two 2-[(3,5-dibromo-2-oxidophenyl)methylamino]ethanol ligands in a slightly distorted octahedral geometry. In the crystal structure, intermolecular O-HÁ Á ÁO hydrogen bonds connect molecules into one-dimensional chains, and there are short intermolecular BrÁ Á ÁBr contacts of 3.592 (1) A ˚.

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.006 A Ê Disorder in main residue R factor = 0.045 wR factor = 0.105 Data-to-parameter ratio = 11.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

{[(5-Bromo-2-oxidophenyl)methyleneamino]
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The title compound, [Cd(C 8 H 6 BrNO 4 S)(C 12 H 8 N 2 )(CH 4 O)], incorporating a Schiff base formed by aminomethanesulfonic acid and 5-bromosalicylaldehyde, was synthesized in a watermethanol solution. In the structure, the Cd II atom is sixcoordinated by one O atom from a methanol molecule, two N