The photodecomposition product l-oxalato-1j 2 O,O 0 0 0 :2j 2 O 0 0 00 0 0 ,O 0 0 00 0 00 0 0 -bis{bis[2-(2-pyridyl)phenylj 2 C,N]iridium(III)}-acetone (1/1.974
Bis[2-(3-methyl-2-pyridyl)phenyl-κ2C1,N](1,1,1-trifluoro-3-thenoylpropan-2-onato-κ2O,O′)iridium(III) ethyl acetate solvate
✍ Scribed by Han, Li-Ping ;Li, Bin ;Liu, Jie ;Ying, Jun
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 887 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, [Ir(C 8 H 4 F 3 O 2 S)(C 12 H 10 N) 2 ]ÁC 4 H 8 O 2 , contains two cyclometallated 3-methyl-2-phenylpyridine ligands and one thenoyltrifluoroacetonate ligand. The central Ir III atom has a distorted octahedral coordination geometry, with the C atoms being cis and the N atoms trans.
📜 SIMILAR VOLUMES
1jN,
l-Oxalato-1j 2 O,O 0 0 0 :2j 2 O 0 0 00 0 0 ,O 0 0 00 0 00 0 0 -bis(chloro{[1-(2pyridyl-jN)ethylidene]hydrazine-jN}copper(II)
The title compound, [Sn 4 (CH 3 ) 8 (C 6 H 5 N 2 O 2 ) 4 O 2 ]Á6H 2 O, is a hydrated cluster containing four Sn atoms, built up by inversion symmetry around the central Sn 2 O 2 ring. The Snatom coordination geometry might be regarded as very distorted SnO 3 C 2 trigonal-bipyramidal or possibly as g